课程介绍

《石油化学》

发布者:肖凡发布时间:2018-05-28

《石油化学》教学大纲

Petroleumchemistry

课程基本信息

CourseInformation

课程名称

Course Name

石油化学

Petroleum chemistry

开课院部

School

化学工程学院

Collegeof Chemical Engineering

院部代码

School Code

03

负责人

Leader

杨朝合

YANG Chaohe

课程团队

Team Members

石油化学

PetroleumChemistry

课程编码

Course Code

03220

学分

Credits

4.0

课内学时

Course Hours

64

理论学时

Lecture Hours

64

实验学时

ExperimentHours

0

上机学时

ProgrammingHours

0

实践学时

PracticeHours

0

课外学时

Home Hours

64

适用专业

Audience

应用化学

AppliedChemistry

授课语言

Language ofInstruction

中文

Chinese

先修课程

Prerequisite

无机及分析化学、有机化学、物理化学、分析化学、高分子化学

Inorganic andanalytical chemistry, Organic chemistry, Physical chemistry,Analytical chemistry, Polymer chemistry

课程简介

CourseDescription

石油化学是应用化学专业的一门主干专业课程。本课程是一门研究石油的组成、性质及其加工成为发动机燃料、润滑剂和石油化学品过程中化学问题的学科,包括石油及其产品的化学组成与性质、石油热转化及催化转化的化学机理、润滑油及添加剂化学、石油化学品合成化学原理等。要求掌握石油化学组成的研究方法及石油的烃类和非烃类组成;我国原油与国外主要原油在化学组成上的特点;主要石油产品的物理性质及化学组成;石油产品物理性质和化学组成之间的关系,以及各种石油产品使用规格的发展趋势;石油加工过程中的主要过程及主要化学反应;石油加工中催化反应及非催化反应的一般规律及其反应历程。课程内容尽可能反映国内外该领域的主要成果和最新进展。通过本课程的学习,为将来从事石油化学、石油化工等相关研究和应用工作打下基础。

Petroleumchemistry is a main professional course of Applied Chemistry.During this course, we mainly study the composition, property andprocessing of petroleum, including chemical composition andproperty of petroleum and petroleum products, chemical mechanismof oil thermal conversion and catalytic conversion, lubricant andadditive chemical, synthesis mechanism of petroleum chemicals.Through this course the following knowledge needs to beunderstood: the chemical composition and non-hydrocarbon andhydrocarbon composition of petroleum; the chemical compositioncharacteristic of China crude oil and foreign crude oil; thechemical composition and physical property of main petroleumproducts; the relationship between petroleum product physicalproperty and chemical composition and the development trend ofpetroleum product using standard; the primary process and themain chemical reaction of petroleum refining; the general regularand reaction mechanism of catalytic and non-catalytic reaction inthe petroleum refining. The main achievement and the latestprogress in the field of home and abroad would be included inthis course. The course could lay a foundation for petroleumchemical, petrochemical engineering and other related researchand work.


课程教学大纲

Course Syllabus

课程目标

LearningOutcomes

课程目标

毕业要求指标点

目标1:在熟悉石油成因的基础上了解石油化学烃类和非烃类组成;掌握我国原油与国外主要原油在化学组成上的特点。

1.2

目标2:了解主要石油产品的物理性质及化学组成;掌握油品的使用性能及化学组分分离或方法,以及各种石油产品使用规格的发展趋势。

1.2

目标3:熟悉石油加工过程中的主要过程及其主要化学反应,了解石油加工中催化反应及热转化反应的一般规律,在热力学及动力学分析的基础上,对其反应历程有一般的了解

1.2

LearningOutcomes

MajorObjectives

Outcomes 1, on the basisof know about the formation reasons of oil, be familiar with thecomposition of oil and its hydrocarbon and non-hydrocarboncomponents; compare with foreign crude oil, the feature of crudeoil from our country should be grasp.

1.2

Outcomes 2, to understandphysical properties and chemical composition of oil products,master oil products usability and chemical composition separationmethods, and the development trends of application specificationsfor various oil products.

1.2

Outcomes 3, knew about thedevelopment history and current situation of petroleum industry,refining industry and petrochemical industry, and be familiarwith development history of petroleum chemistry.

1.2

教学内容

Topics

绪论(共2学时)

石油工业的历史与现状、炼油工业的历史与现状、石油化学工业的历史与现状、石油化学学科沿革。

第一章石油化学的组成(共8学时)

本章重点难点:不同类型的石油化学组成的特点、石油中胶质与沥青质的组成特性、石油胶体化学的特点。

1.1原油的一般性质、元素组成、馏分组成和分类

原油的基础知识。

1.2石油的烃类组成                                        

石油烃类组成的表示方法;石油天然气的单体烃组成、汽油馏分的单体烃组成与族组成、煤柴油馏分的烃族组成、减压渣油的族组成、减压馏分与减压渣油的结构族组成等基础知识。

1.3石油中的含硫化合物

硫在石油及其各馏分中的分布及存在形态。

1.4石油中的含氮化合物

氮在石油及其各馏分中的分布及存在形态。

1.5石油中的含氧化合物

石油中酸性含氧化合物的分布状况、石油中含氧化合物的组成、石油酸的性质及其利用。

1.6石油中的微量元素

石油中微量元素的组成及其分布、石油中微量元素的存在形态。

1.7石油中的胶状沥青状物质

胶质与沥青质的元素组成、平均相对分子质量及结构特征、石油胶体分散体系。

第二章石油及天然气成因(共2学时)

本章重点难点:石油与天然气的现代有机成因说及其生成过程

2.1粘土矿物的晶体构造与粘土的带电性

石油的无机成因说、有机成因说,生成石油的原始物质、生油环境,沉积盆地中有机残体的演化与油气生成的阶段性,石油的运移和富集。

2.2粘土的水化膨胀性与粘土的吸附及凝聚性

正构烷烃的形成、异构烷烃的形成、环烷烃的形成以及芳香烃的形成。

2.3天然气的成因

生物成因气、油型气、煤型气及非烃气体的成因。

第三章石油及油品的物理性质(共6学时)

本章重点难点:石油及油品的物理性质如平均相对分子质量、密度、折射率、黏度、黏温性质与其化学组成的关系

3.1馏程、实沸点蒸馏曲线和平衡气化曲线

3.2平均相对分子质量

平均相对分子质量的定义、数均相对分子质量的测定方法、石油及其馏分的数均相对分子质量。

3.3密度和相对密度

石油及其油品的密度与相对密度定义与测定方法、液体油品相对密度与温度、压力的关系、相对密度与化学组成的关系、石油及其馏分的相对密度、特性因数与相关指数的定义。

3.4光学性质

折射率的测定方法、折射率与化学组成的关系、石油馏分及其组分的折射率。

3.5粘度

黏度的定义、测定方法、黏度与化学组成的关系、黏度与温度的关系、黏温性质与分子结构的关系、石油及其馏分的黏度和黏-温性质

3.6石油的热性质

石油的比热容、焓、蒸发热、熔化热和燃烧热、石油及其产品的浊点、结晶点、倾点及凝点、石油产品的闪点、燃点和自燃点。

第四章石油化学组成分离及分析方法(共4学时)

本章重点难点:气相色谱与液相色谱的基本原理及其在石油组成分析中的应用

4.1精密分馏、分子蒸馏

精密分馏的特点、分子蒸馏的基本原理及其应用。

4.2 气相色谱

气相色谱的基本原理、气相色谱仪、气相色谱法在石油工业中的应用

4.3 液相及超临界流体色谱法

液固吸附色谱基本原理及其在石油分析中的应用、离子交换色谱法、凝胶渗透色谱法、分配及键合相色谱法、高效液相色谱法、超临界流体色谱法。

4.4 元素分析方法

碳和氢含量的测定、硫含量的测定、氮含量的测定、氧含量的测定、微量元素含量的测定。

4.5 由物理性质关联化学组成的方法

用苯胺点法测定汽油馏分的族组成、用n-d-M(折射率-密度-相对分子质量)法测定减压馏分的结构族组成、用密度法测定重油的结构族组成。

4.6 近代物理分析方法

红外光谱法、核磁共振波谱法、质谱法的基本原理及其在石油组成分析中的应用。

第五章石油产品的使用性能及其与化学组成的关系(共10学时)

本章重点难点:汽油、柴油、喷气燃料、内燃机润滑油的使用性能与其化学组成的关系。

5.1汽油

汽油机的工作原理、汽油的蒸发性、安定性、抗爆性、汽油的质量演变过程以及牌号、醇类汽油机燃料。

5.2柴油

柴油机的工作过程、柴油的自燃性、蒸发性、流动性、安定性、柴油的质量标准及牌号、生物柴油。

5.3喷气燃料(航空煤油)

喷气发动机的工作过程、喷气燃料的燃烧性能、喷气燃料的安定性、低温性能、腐蚀性、洁净度、起电性、润滑性。

5.4润滑油

润滑的种类及润滑油的分类、内燃机润滑油使用性能与其化学组成的关系。5.5石油蜡                                                               

石油蜡的分类、石蜡与微晶蜡的使用性能与化学组成、石腊与微晶蜡的品种和用途。

5.6石油沥青

石油沥青的流变性、石油沥青的化学组成、胶体结构与使用性能的关系、石油沥青的分类。

第六章热转化(共6学时)

本章重点难点:各族烃类的热转化反应、反应机理及反应动力学、高温裂解、减黏裂化、延迟焦化的工艺的基本原理、反应条件对这些热转化工艺过程的影响。

6.1石油的热转化反应

烷烃、环烷烃、芳香烃、烯烃、非烃类的热转化反应。

6.2烃类热解反应的历程

自由基链反应历程、自由基非链反应历程、分子反应历程。

6.3烃类热解反应动力学

各种单体烃类的热反应动力学、烃类混合物的热解反应动力学。

6.4高温裂解

高温裂解的基本原理、原料与反应条件对高温裂解的影响、烃类高温裂解的反应动力学特征。

6.5减粘裂化

减黏裂化的原理、渣油的减黏裂化反应、渣油在减黏裂化反应中过程中胶体性质的变化、渣油减黏裂化的影响因素。

6.6延迟焦化

延迟焦化的原理、原料及反应条件对延迟焦化的影响、石油焦碳的生成过程。

第七章催化裂化(共8学时)

本章重点难点:催化裂化的正碳离子反应历程、各族烃类以及石油馏分的催化裂化反应、催化裂化反应的催化剂组成结构以及催化性能、催化剂、原料以及反应条件对石油馏分催化裂化的影响。

7.1概述

催化裂化工艺的发展过程、催化裂化工艺的基本原理

7.2催化裂化反应

催化裂化的正碳离子反应历程、各族烃类与石油馏分的催化裂化反应及其反应热

7.3催化裂化催化剂

裂化催化剂的组成结构与使用性能、催化裂化催化剂的助剂

7.4催化裂化反应的影响因素

催化裂化的影响、原料组成的影响、反应条件的影响

7.5催化裂化反应及再生动力学模型

催化裂化反应动力学模型、催化裂化催化剂再生动力学模型

7.6多产低碳烯烃的催化裂化新工艺

最大量生产丙烯技术、生产低碳烯烃兼顾汽油的技术、生产乙烯与丙烯为主的催化热裂解。

第八章催化裂化(共7学时)

本章的重点难点:各族烃类的催化重整反应、催化重整反应热力学与动力学、催化重整催化剂的组成、催化剂的失活与再生、反应原料与反应条件对催化重整反应的影响。

8.1概述

催化重整工艺的发展及工艺原理。

8.2催化重整的化学反应

六员环烷烃的脱氢反应、各族烃类的异构化反应、烷烃脱氢环化反应、氢解及加氢裂化反应、积炭反应。

8.3催化重整催化剂

催化重整催化剂的双功能特性、催化重整催化剂的组成、催化重整催化剂的失活与再生。

8.4催化重整原料的影响

馏分范围的选定、烃类组成与杂质含量的影响。

8.5反应条件对催化重整的影响

反应温度、反应压力、空间速度、氢油比影响。

8.6催化重整反应及再生动力学模型

催化重整反应动力学与再生动力学模型。

第九章催化加氢(共7学时)

本章的重点难点:加氢处理与加氢裂化反应及其反应动力学与反应热力学、加氢处理与加氢裂化工艺的催化剂组成与性能、加氢工艺的影响因素。

9.1加氢处理

加氢处理反应、加氢处理催化剂、加氢处理的影响因素。

9.2加氢裂化

加氢裂化概述、加氢裂化反应、加氢裂化催化剂、加氢裂化的影响因素。

9.3润滑油加氢、临氢降凝和重油加氢

润滑油加氢补充精制与加氢处理、催化加氢脱蜡、柴油催化加氢脱蜡、润加油催化加氢脱蜡、异构脱蜡、重油加氢的特点以及重油加氢工艺。

9.4氢气的制取

烃类水蒸气转化法制氢、重油部分氧化法制氢

第十章高辛烷值汽油组分的制取(共4学时)

本章的重点难点:烃类的烷基化反应、烷基化反应的影响因素、催化醚化反应及其影响因素、催化异构化反应、异构化催化剂、催化叠合反应及其影响因素。

10.1催化烷基化

烷基化反应、原料对烷基化反应的影响,硫酸烷基化、氢氟酸烷基化、催化烷基化的新进展。

10.2催化醚化

催化醚化反应、醚化催化剂、醚化反应的影响因素。

10.3催化异构化

异构化反应、异构化催化剂。

10.4催化叠合

叠合反应、非选择性催化叠合、选择性催化叠合。

Introduction(2 hours)

Thehistory and present situation of petroleum industry, the historyand present situation of oil refining industry, the history andpresent situation of petrochemical industry and the evolution ofpetroleum chemistry.

ChapterI Composition of petroleum chemistry (8 hours)

Keypoints of this chapter: the characteristics of different types ofpetroleum chemistry, the composition of colloidal and asphalticproperties and the characteristics of petroleum colloidalchemistry.

1.1General properties, elemental composition, fraction compositionand classification of crude oil

Basicknowledge about crude oil

1.2Petroleum hydrocarbons

Methodsfor the representation of petroleum hydrocarbons; Monomerhydrocarbon composition of oil and gas, monomer hydrocarboncomposition and group composition of gasoline fraction,hydrocarbon group composition of coal diesel fraction, groupcomposition of vacuum residuum, the structure group compositionof the vacuum distillate and vacuum residuum, and other basicknowledge.

1.3Sulfur compounds in petroleum

Thedistribution and existence of sulfur in petroleum and itsdistillates.

1.4Nitrogen compounds in petroleum

Thedistribution and existence of nitrogen in petroleum and itsdistillates.

1.5Oxygen compounds in petroleum

Thedistribution of oxygen-containing compounds in petroleum, thecomposition of oxygen-containing compounds in petroleum, theproperties and utilization of petroleum acids.

1.6Trace elements in petroleum

Thecomposition and distribution of trace elements in petroleum, theexistence of trace elements in petroleum.

1.7Colloidal bituminous material in petroleum

Theelemental composition, average relative molecular mass, andstructure characteristics of colloidal and asphaltic, oilcolloidal dispersion system.

Chapterii Causes of oil and gas (2 hours)

Keypoints of this chapter: the modern organic genesis and formationprocess of oil and natural gas.

2.1Crystal structure of clay minerals and the electrification ofclay

Inorganicand organic origin of Oil, the raw material of oil, sourceenvironment, evolution and the phases of organic residues in thesedimentary basin, the migration and enrichment of oil.

2.2Hydration, adsorption, and coagulation of clay

Theformation of alkanes, the formation of isomers, the formation ofnaphthene and the formation of aromatic hydrocarbons.

2.3Genesis of natural gas

Thegenesis of biogenic gas, oil type gas, coal gas andnon-hydrocarbon gases.

Chapteriii Physical properties of oil and oil products (6 hours)

Keypoints of this chapter: the physical properties of oil and oilproducts: molecular weight, density, refractive index, viscosity,viscosity and chemical composition.

3.1The distillation curve, the true boiling point distillationcurve, and the equilibrium gasification curve.

3.2Average relative molecular mass

Thedefinition of average relative molecular weight, thedetermination methods of number relative molecular mass, thenumber relative molecular mass of oil and its fraction.

3.3Density and relative density

Thedefinition and measurement method of oils, the relation betweenrelative density of liquid oil and temperature and pressure, therelation between relative density and chemical composition,  therelative density of petroleum and its distillate, the definitionof characteristic factor and correlation index.

3.4Optical properties

Thedetermination method of refractive index, the relationshipbetween refractive index and chemical composition, the refractiveindex of petroleum fractions and their components.

3.5Viscosity

Thedefinition and determination method of viscosity, therelationship between viscosity and chemical composition, therelationship between viscosity and temperature, the relationshipbetween viscosity and molecular structure, the viscosity andviscosity-temperature properties of petroleum and its fractions.

3.6Thermal properties of oil

Thespecific heat capacity, enthalpy, evaporation heat, melting heatand combustion heat of oils, the turbidity point, crystallizationpoint, pour point and freezing point of oils, the flash points,ignition points and spontaneous combustion points of oils.

Chapteriv Separation and analysis of petroleum chemistry (4 hours)

Keypoints of this chapter: the basic principles of gaschromatography and liquid chromatography, and their applicationsin petroleum composition analysis.

4.1Precise fractionation and molecular distillation

Thecharacteristics of precise fractionation, the basic principle ofmolecular distillation and its application.

4.2Gas chromatography

Thebasic principle of gas chromatography, gas chromatograph, theapplication of gas chromatography in petroleum industry

4.3Liquid phase and supercritical fluid chromatography

Basicprinciple of liquid-solid adsorption chromatography and itsapplication in oil analysis, ion exchange chromatography, gelpermeation chromatography, allocation and bonded phasechromatography, high performance liquid chromatography,supercritical fluid chromatography.

4.4Elemental analysis method

Determinationof carbon and hydrogen content, determination of sulfur content,determination of nitrogen content, determination of oxygencontent, determination of trace element content.

4.5Method of associating chemical composition with physicalproperties

Usingthe aniline point method to test the group composition ofgasoline fraction, using the n - d - M (refractive index,density, relative molecular mass) method for determining thestructure of vacuum distillate composition, using the densitymethod to test the structure of heavy oil group composition.

4.6Modern physical analysis method

Thebasic principles of infrared spectroscopy, nuclear magneticresonance spectroscopy, mass spectrometry and their applicationsin petroleum composition analysis

Chapterv Performance of petroleum products and their relationship withchemical composition (10 hours)

Keypoints of this chapter: the use performance of gasoline, dieseloil, jet fuel, internal combustion engine oil and its chemicalcomposition.

5.1Gasoline

Theworking principle of gasoline engine, evaporation, stability,explosion resistance of gasoline, quality evolution process ofgasoline, and fuel grade and alcohol gasoline engine.

5.2Diesel

Theworking process of diesel engine, the spontaneous combustion,evaporation, fluidity, stability of diesel, diesel qualitystandard and brand number, biodiesel.

5.3Jet fuel (aviation kerosene)

Theworking process of jet engine, combustion performance of jetfuel, stability, low temperature performance, corrosion,cleanliness, electrification and lubricity of jet fuel.

5.4Lubricating oil

Typesof lubrication and classification of lubricants, the relationshipbetween oil use performance and chemical composition.

5.5Petroleum wax

Classificationof petroleum wax, the use performance and chemical composition ofparaffin wax and microcrystalline wax, the variety and use of waxand paraffin wax.

5.6Petroleum asphalt

Therheological of petroleum asphalt and chemical composition ofpetroleum asphalt, the relationship between colloidal structureand performance, the classification of petroleum asphalt.

Chaptervi Heat transfer (6 hours)

Keypoints of this chapter: thermaltransformation reactions of various kinds of hydrocarbons,reaction mechanism and kinetics, the basic principle ofpyrolysis, viscosity reduction and delayed coking process,effects of reaction conditions on these thermal transformationprocesses.

6.1 Heat transfer reactionof oils

Heattransfer reactions of alkanes, naphthene, aromatic hydrocarbons,olefins, and non-hydrocarbon.

6.2Process of hydrocarbon pyrolysis reaction

Theprocess of free radical chain reaction, free radical non-chainreaction and molecular reaction.

6.3Hydrothermal reaction kinetics of hydrocarbons

Thermalreaction kinetics of various monomer hydrocarbons, pyrolyticreaction kinetics of hydrocarbon mixtures.

6.4Pyrolysis

Thebasic principle of pyrolysis, influences of raw materials andreaction conditions on pyrolysis, reaction kinetics of hightemperature pyrolysis of hydrocarbons.

6.5 Viscositybreaking

Theprinciple of viscosity breaking, the viscosity breaking ofresidual oil, the property change of colloids in the process ofviscosity breaking, influence factors of residual oil viscositycracking.

6.6Delayed coking

Theprinciple of delayed coking, effects of raw materials andreaction conditions on delayed coking, the formation of petroleumcoke.

Chaptervii Catalytic cracking (8 hours)

Keypoints of this chapter: processof catalytic cracking positive carbon ion reaction, catalyticcracking reaction of hydrocarbon and petroleum distillates,composition structure and catalytic performance of catalyticcracking reaction catalyst,  influencesof catalyst, raw material and reaction conditions on catalyticcracking of petroleum distillates.

7.1Overview

Thedevelopment process of catalytic cracking process, the basicprinciple of catalytic cracking process.

7.2Catalytic cracking reaction

Theprocess of catalytic cracking positive carbon ion reaction, thecatalytic cracking reaction and heat reaction of hydrocarbon andpetroleum fractions.

7.3Catalytic cracking catalyst

Thecomposition and use performance of cracking catalysts, catalyticcracking catalyst additives.

7.4Influence factors of catalytic cracking reaction

Theinfluence of catalytic cracking, the composition of rawmaterials, and reaction conditions.

7.5Catalytic cracking reaction and regenerative dynamics model

Catalyticcracking reaction kinetics model and catalytic cracking catalystregeneration kinetics model.

7.6A new catalytic cracking process for low - carbon olefin

Thetechnology of producingpropylene,the technology of producing low-carbon olefin and gasoline, thetechnology of producing ethylene and propylene.

Chapterviii Catalytic reforming (7 hours)

Keypoints of this chapter: the catalytic reforming reaction of allkinds of hydrocarbons, thermodynamics and kinetics of catalyticreforming reaction, the composition of catalytic reformingcatalyst, the inactivation and regeneration of the catalyst,effects of reaction materials and reaction conditions oncatalytic reforming reaction.

8.1Overview

Developmentand principle of catalytic reforming process.

8.2Chemical reaction of catalytic reforming

Thedehydrogenation of six member naphthene, the isomerization ofhydrocarbon groups, the dehydrocyclization reaction, hydrolysisand hydrocracking reaction, carbon deposition reaction ofalkanes.

8.3Catalytic reforming catalyst

Bifunctionalcharacteristics of catalytic reforming catalyst, the compositionof catalytic reforming catalyst, the deactivation andregeneration of catalytic reforming catalyst.

8.4Influence of catalytic reforming raw materials

Theselection of the fraction range, the influences of hydrocarboncomposition and impurity content.

8.5Effect of reaction conditions on catalytic reforming

Effectsof reaction temperature, reaction pressure, space speed, hydrogenoil ratio.

8.6Catalytic reforming reaction and regenerative dynamics model

Kineticsand regenerative dynamics model of catalytic reforming.

Chapterix Catalytic hydrogenation (7 hours)

Keypoints of this chapter: hydro-treating and hydrocrackingreaction, reaction kinetics and reaction thermodynamics, catalystcomposition and performance of hydro-treating and hydrocracking,influence factors of hydrogenation process.

9.1Hydro-treating

Hydro-treatingreaction, hydro-treating catalysts, effects of hydrogenationtreatment.

9.2Hydrocracking

Hydrocrackingoverview, hydrocracking reaction, hydrocracking catalyst,hydrocracking influence factors.

9.3Lube oil hydrogenation, hydrogenation and heavy oil hydrogenation

Lubeoil hydrogenation and hydrogenation treatment, catalytichydro-dewaxing, catalytic hydro-dewaxing of diesel and lube oil,iso-dewaxing, the characteristics of heavy oil hydrogenation andthe process of heavy oil hydrogenation.

9.4Hydrogen production

Hydrocarbon-watervapor transformation method, partial oxidation process of heavyoil.

Chapterx Production of high octane gasoline components (4 hours)

Keypoints of this chapter: alkylation of hydrocarbons, influencefactors of alkylation reaction, catalytic etherification and itsinfluencing factors, catalytic isomerization, isomerizationcatalyst, catalytic polymerization reaction and its influencingfactors.

10.1Catalytic alkylation

Alkylationreaction, the influence of raw materials on alkylation reaction,sulfuric acid alkylation, hydrofluoric acid alkylation, newprogress in catalytic alkylation.

10.2Catalytic etherification

Catalyticetherification, etherification catalyst, the influence factors ofetherification reaction.

10.3Catalytic isomerization

Isomerizationreaction, isomerization catalyst.

10.4Catalytic polymerization

Thepolymerization reaction, the non-selective catalyticpolymerization, the selective catalytic polymerization.



教学进度及要求

ClassSchedule & Requirements

内容

课内

学时

教学方式

课外

学时

课外环节

课程目标

1.0

2

讲授

2

自学

1

1.1

2

讲授

2

自学

1

1.2

1

讲授

1

自学

1

1.3

1

讲授

1

自学

1

1.4

1

讲授

1

自学

1

1.5

1

讲授

1

自学

1

1.6

1

讲授

1

自学

1

1.7

1

讲授

1

作业

1

2.1

1

讲授

1

自学

1

2.2

0.5

讨论

0.5

自学

1

2.3

0.5

讲授

0.5

作业

1

3.1

1

讲授

1

作业

2

3.2

1

讲授

1

自学

2

3.3

1

讲授

1

自学

2

3.4

0.5

讨论

0.5

自学

2

3.5

1.5

讲授

1.5

自学

2

3.6

1

讲授

1

作业

2

4.1

2

讲授

2

自学

2

4.2

2

讲授

2

自学

2

4.3

1

讲授

1

自学

2

4.4

1

讲授

1

自学

2

4.5

2

讲授

2

作业

2

4.6

1

讲授

1

作业

2

5.1

3

讲授

3

自学

2

5.2

2

讲授

2

自学

2

5.3

2

讲授

2

自学

2

5.4

1

讲授

1

自学

2

5.5

1

讲授

1

自学

2

5.6

1

讲授

1

作业

2

6.1

1

讲授

1

自学

3

6.2

1

讲授

1

自学

3

6.3

1

讲授

1

自学

3

6.4

1

讲授

1

自学

3

6.5

1

讲授

1

自学

3

6.6

2

讲授

1

作业

3

7.1

1

讲授

1

自学

3

7.2

2

讲授

2

自学

3

7.3

2

讲授

2

自学

3

7.4

2

讲授

2

自学

3

7.5

1

讲授

1

自学

3

7.6

1

讲授

1

作业

3

8.1

0.5

讲授

0.5

自学

3

8.2

2

讲授

2

自学

3

8.3

2

讲授

2

自学

3

8.4

1

讲授

1

自学

3

8.5

1

讲授

1

自学

3

8.6

0.5

讲授

0.5

作业

3

9.1

2

讲授

2

自学

3

9.2

2

讲授

2

自学

3

9.3

2

讲授

2

自学

3

9.4

1

讲授

1

作业

3

10.1

1

讲授

1

自学

3

10.2

1

讲授

1

自学

3

10.3

1

讲授

1

自学

3

10.4

1

讲授

1

作业

3

Topics

Course

Hours

TeachingMethods

Home

Hours

Assignment

Outcomes

0

2

Teaching

1

Reading

1

1.1

2

Teaching

1

Reading

1

1.2

1

Teaching

1

Reading

1

1.3

1

Teaching

1

Reading

1

1.4

1

Teaching

1

Reading

1

1.5

1

Teaching

1

Reading

1

1.6

1

Teaching

1

Reading

1

1.7

1

Teaching

1

Homework

1

2.1

1

Teaching

1

Reading

1

2.2

0.5

Discussion

0.5

Reading

1

2.3

0.5

Teaching

0.5

Homework

1

3.1

1

Teaching

1

Reading

2

3.2

1

Teaching

1

Reading

2

3.3

1

Teaching

1

Reading

2

3.4

0.5

Discussion

0.5

Reading

2

3.5

1.5

Teaching

1.5

Reading

2

3.6

1

Teaching

1

Homework

2

4.1

2

Teaching

2

Reading

2

4.2

2

Teaching

2

Reading

2

4.3

1

Teaching

1

Reading

2

4.4

1

Teaching

1

Reading

2

4.5

2

Teaching

2

Reading

2

4.6

1

Teaching

1

Homework

2

5.1

3

Teaching

3

Reading

2

5.2

2

Teaching

2

Reading

2

5.3

2

Teaching

2

Reading

2

5.4

1

Teaching

1

Reading

2

5.5

1

Teaching

1

Reading

2

5.6

1

Teaching

1

Homework

2

6.1

1

Teaching

1

Reading

3

6.2

1

Teaching

1

Reading

3

6.3

1

Teaching

1

Reading

3

6.4

1

Teaching

1

Reading

3

6.5

1

Teaching

1

Reading

3

6.6

2

Teaching

1

Homework

3

7.1

1

Teaching

1

Reading

3

7.2

2

Teaching

2

Reading

3

7.3

2

Teaching

2

Reading

3

7.4

2

Teaching

2

Reading

3

7.5

1

Teaching

1

Reading

3

7.6

1

Teaching

1

Homework

3

8.1

0.5

Teaching

0.5

Reading

3

8.2

2

Teaching

2

Reading

3

8.3

2

Teaching

2

Reading

3

8.4

1

Teaching

1

Reading

3

8.5

1

Teaching

1

Reading

3

8.6

0.5

Teaching

0.5

Homework

3

9.1

2

Teaching

2

Reading

3

9.2

2

Teaching

2

Reading

3

9.3

2

Teaching

2

Reading

3

9.4

1

Teaching

1

Reading

3

10.1

1

Teaching

1

Reading

3

10.2

1

Teaching

1

Reading

3

10.3

1

Teaching

1

Reading

3

10.4

1

Teaching

1

Reading

3

考核方式

Grading

评价环节

比例

环节1:课堂出勤

10%

环节2:课堂讨论

10%

环节3:课程作业

20%

环节4:考试

60%

Evaluation

Percentage

Evaluation1Attendance

10%

Evaluation2Discussion

10%

Evaluation3Homework

20%

Evaluation4Test

60%

教材及参考资料

Textbooks &Other Materials

1.《石油化学》,梁文杰等编著,中国石油大学出版社,2009

2.《石油炼制工程》,林世雄编著,石油工业出版社,2000,“九五”国家级重点教材;

3.《重质油化学》,梁文杰编著,石油大学出版社,2000年,“九五”省部级重点教材;

4.《石油组成与转化化学》,佟曼丽编著,石油大学出版社,1996年;

5.《石油炼制化学》,吴祖光等编,兰州大学出版社,1989年;

6.《中国炼油技术》(第二版),侯祥麟主编,中国石化出版社,2001年;

7.《石油沥青质》,秦匡宗编著,石油工业出版社,2002年,国家统编;

8.《石油和石油产品中非烃类化合物》,刘长久编著,中国石化出版社,1991年;

9.《绿色石化技术的科学与工程基础》,闵恩泽编著,中国石化出版社,2002年;

1. Wenjie Liang, PetroleumChemistry, ChinaUniversity of Petroleum Press, 2009.

2. Shixiong Lin, PetroleumRefining Engineering, PetroleumIndustry Press, 2000, “Ninth five-year” national keytextbook.

3. Wenjie Liang, HeavyOil Chemistry,Petroleum University Press, 2000, “Ninth five-year”provincial key textbook.

4. Manli, Tong, Petroleumcomposition and conversion chemistry,Petroleum University Press, 1996.

5.Zuguang, Wu, PetroleumRefining Chemistry,Lanzhou University Press, 1989.

6.Xianglin, Hou, ChinaRefining technology, ChinaPetrochemical Press, 2001.

7. Kuangzong, Qin, PetroleumAsphaltene,Petroleum Industry Press, 2002, the state uniform textbooks.

8. Changjiu, Liu, Petroleumand non-hydrocarbon compounds in oil products, ChinaPetrochemical Press, 1991.

9.Enze, Min, Scienceand engineering foundation of green petrochemical technology,ChinaPetrochemical Press, 2002.

其它

More


备注

Notes


大纲执笔人

Author

刘东

LIU Dong

审核人(/教研室主任)

Approved by

刘东,殷长龙

LIU DongYINChanglong