Introduction(2 hours) Thehistory and present situation of petroleum industry, the historyand present situation of oil refining industry, the history andpresent situation of petrochemical industry and the evolution ofpetroleum chemistry. ChapterI Composition of petroleum chemistry (8 hours) Keypoints of this chapter: the characteristics of different types ofpetroleum chemistry, the composition of colloidal and asphalticproperties and the characteristics of petroleum colloidalchemistry. 1.1General properties, elemental composition, fraction compositionand classification of crude oil Basicknowledge about crude oil 1.2Petroleum hydrocarbons Methodsfor the representation of petroleum hydrocarbons; Monomerhydrocarbon composition of oil and gas, monomer hydrocarboncomposition and group composition of gasoline fraction,hydrocarbon group composition of coal diesel fraction, groupcomposition of vacuum residuum, the structure group compositionof the vacuum distillate and vacuum residuum, and other basicknowledge. 1.3Sulfur compounds in petroleum Thedistribution and existence of sulfur in petroleum and itsdistillates. 1.4Nitrogen compounds in petroleum Thedistribution and existence of nitrogen in petroleum and itsdistillates. 1.5Oxygen compounds in petroleum Thedistribution of oxygen-containing compounds in petroleum, thecomposition of oxygen-containing compounds in petroleum, theproperties and utilization of petroleum acids. 1.6Trace elements in petroleum Thecomposition and distribution of trace elements in petroleum, theexistence of trace elements in petroleum. 1.7Colloidal bituminous material in petroleum Theelemental composition, average relative molecular mass, andstructure characteristics of colloidal and asphaltic, oilcolloidal dispersion system. Chapterii Causes of oil and gas (2 hours) Keypoints of this chapter: the modern organic genesis and formationprocess of oil and natural gas. 2.1Crystal structure of clay minerals and the electrification ofclay Inorganicand organic origin of Oil, the raw material of oil, sourceenvironment, evolution and the phases of organic residues in thesedimentary basin, the migration and enrichment of oil. 2.2Hydration, adsorption, and coagulation of clay Theformation of alkanes, the formation of isomers, the formation ofnaphthene and the formation of aromatic hydrocarbons. 2.3Genesis of natural gas Thegenesis of biogenic gas, oil type gas, coal gas andnon-hydrocarbon gases. Chapteriii Physical properties of oil and oil products (6 hours) Keypoints of this chapter: the physical properties of oil and oilproducts: molecular weight, density, refractive index, viscosity,viscosity and chemical composition. 3.1The distillation curve, the true boiling point distillationcurve, and the equilibrium gasification curve. 3.2Average relative molecular mass Thedefinition of average relative molecular weight, thedetermination methods of number relative molecular mass, thenumber relative molecular mass of oil and its fraction. 3.3Density and relative density Thedefinition and measurement method of oils, the relation betweenrelative density of liquid oil and temperature and pressure, therelation between relative density and chemical composition, therelative density of petroleum and its distillate, the definitionof characteristic factor and correlation index. 3.4Optical properties Thedetermination method of refractive index, the relationshipbetween refractive index and chemical composition, the refractiveindex of petroleum fractions and their components. 3.5Viscosity Thedefinition and determination method of viscosity, therelationship between viscosity and chemical composition, therelationship between viscosity and temperature, the relationshipbetween viscosity and molecular structure, the viscosity andviscosity-temperature properties of petroleum and its fractions. 3.6Thermal properties of oil Thespecific heat capacity, enthalpy, evaporation heat, melting heatand combustion heat of oils, the turbidity point, crystallizationpoint, pour point and freezing point of oils, the flash points,ignition points and spontaneous combustion points of oils. Chapteriv Separation and analysis of petroleum chemistry (4 hours) Keypoints of this chapter: the basic principles of gaschromatography and liquid chromatography, and their applicationsin petroleum composition analysis. 4.1Precise fractionation and molecular distillation Thecharacteristics of precise fractionation, the basic principle ofmolecular distillation and its application. 4.2Gas chromatography Thebasic principle of gas chromatography, gas chromatograph, theapplication of gas chromatography in petroleum industry 4.3Liquid phase and supercritical fluid chromatography Basicprinciple of liquid-solid adsorption chromatography and itsapplication in oil analysis, ion exchange chromatography, gelpermeation chromatography, allocation and bonded phasechromatography, high performance liquid chromatography,supercritical fluid chromatography. 4.4Elemental analysis method Determinationof carbon and hydrogen content, determination of sulfur content,determination of nitrogen content, determination of oxygencontent, determination of trace element content. 4.5Method of associating chemical composition with physicalproperties Usingthe aniline point method to test the group composition ofgasoline fraction, using the n - d - M (refractive index,density, relative molecular mass) method for determining thestructure of vacuum distillate composition, using the densitymethod to test the structure of heavy oil group composition. 4.6Modern physical analysis method Thebasic principles of infrared spectroscopy, nuclear magneticresonance spectroscopy, mass spectrometry and their applicationsin petroleum composition analysis Chapterv Performance of petroleum products and their relationship withchemical composition (10 hours) Keypoints of this chapter: the use performance of gasoline, dieseloil, jet fuel, internal combustion engine oil and its chemicalcomposition. 5.1Gasoline Theworking principle of gasoline engine, evaporation, stability,explosion resistance of gasoline, quality evolution process ofgasoline, and fuel grade and alcohol gasoline engine. 5.2Diesel Theworking process of diesel engine, the spontaneous combustion,evaporation, fluidity, stability of diesel, diesel qualitystandard and brand number, biodiesel. 5.3Jet fuel (aviation kerosene) Theworking process of jet engine, combustion performance of jetfuel, stability, low temperature performance, corrosion,cleanliness, electrification and lubricity of jet fuel. 5.4Lubricating oil Typesof lubrication and classification of lubricants, the relationshipbetween oil use performance and chemical composition. 5.5Petroleum wax Classificationof petroleum wax, the use performance and chemical composition ofparaffin wax and microcrystalline wax, the variety and use of waxand paraffin wax. 5.6Petroleum asphalt Therheological of petroleum asphalt and chemical composition ofpetroleum asphalt, the relationship between colloidal structureand performance, the classification of petroleum asphalt. Chaptervi Heat transfer (6 hours) Keypoints of this chapter: thermaltransformation reactions of various kinds of hydrocarbons,reaction mechanism and kinetics, the basic principle ofpyrolysis, viscosity reduction and delayed coking process,effects of reaction conditions on these thermal transformationprocesses. 6.1 Heat transfer reactionof oils Heattransfer reactions of alkanes, naphthene, aromatic hydrocarbons,olefins, and non-hydrocarbon. 6.2Process of hydrocarbon pyrolysis reaction Theprocess of free radical chain reaction, free radical non-chainreaction and molecular reaction. 6.3Hydrothermal reaction kinetics of hydrocarbons Thermalreaction kinetics of various monomer hydrocarbons, pyrolyticreaction kinetics of hydrocarbon mixtures. 6.4Pyrolysis Thebasic principle of pyrolysis, influences of raw materials andreaction conditions on pyrolysis, reaction kinetics of hightemperature pyrolysis of hydrocarbons. 6.5 Viscositybreaking Theprinciple of viscosity breaking, the viscosity breaking ofresidual oil, the property change of colloids in the process ofviscosity breaking, influence factors of residual oil viscositycracking. 6.6Delayed coking Theprinciple of delayed coking, effects of raw materials andreaction conditions on delayed coking, the formation of petroleumcoke. Chaptervii Catalytic cracking (8 hours) Keypoints of this chapter: processof catalytic cracking positive carbon ion reaction, catalyticcracking reaction of hydrocarbon and petroleum distillates,composition structure and catalytic performance of catalyticcracking reaction catalyst, influencesof catalyst, raw material and reaction conditions on catalyticcracking of petroleum distillates. 7.1Overview Thedevelopment process of catalytic cracking process, the basicprinciple of catalytic cracking process. 7.2Catalytic cracking reaction Theprocess of catalytic cracking positive carbon ion reaction, thecatalytic cracking reaction and heat reaction of hydrocarbon andpetroleum fractions. 7.3Catalytic cracking catalyst Thecomposition and use performance of cracking catalysts, catalyticcracking catalyst additives. 7.4Influence factors of catalytic cracking reaction Theinfluence of catalytic cracking, the composition of rawmaterials, and reaction conditions. 7.5Catalytic cracking reaction and regenerative dynamics model Catalyticcracking reaction kinetics model and catalytic cracking catalystregeneration kinetics model. 7.6A new catalytic cracking process for low - carbon olefin Thetechnology of producingpropylene,the technology of producing low-carbon olefin and gasoline, thetechnology of producing ethylene and propylene. Chapterviii Catalytic reforming (7 hours) Keypoints of this chapter: the catalytic reforming reaction of allkinds of hydrocarbons, thermodynamics and kinetics of catalyticreforming reaction, the composition of catalytic reformingcatalyst, the inactivation and regeneration of the catalyst,effects of reaction materials and reaction conditions oncatalytic reforming reaction. 8.1Overview Developmentand principle of catalytic reforming process. 8.2Chemical reaction of catalytic reforming Thedehydrogenation of six member naphthene, the isomerization ofhydrocarbon groups, the dehydrocyclization reaction, hydrolysisand hydrocracking reaction, carbon deposition reaction ofalkanes. 8.3Catalytic reforming catalyst Bifunctionalcharacteristics of catalytic reforming catalyst, the compositionof catalytic reforming catalyst, the deactivation andregeneration of catalytic reforming catalyst. 8.4Influence of catalytic reforming raw materials Theselection of the fraction range, the influences of hydrocarboncomposition and impurity content. 8.5Effect of reaction conditions on catalytic reforming Effectsof reaction temperature, reaction pressure, space speed, hydrogenoil ratio. 8.6Catalytic reforming reaction and regenerative dynamics model Kineticsand regenerative dynamics model of catalytic reforming. Chapterix Catalytic hydrogenation (7 hours) Keypoints of this chapter: hydro-treating and hydrocrackingreaction, reaction kinetics and reaction thermodynamics, catalystcomposition and performance of hydro-treating and hydrocracking,influence factors of hydrogenation process. 9.1Hydro-treating Hydro-treatingreaction, hydro-treating catalysts, effects of hydrogenationtreatment. 9.2Hydrocracking Hydrocrackingoverview, hydrocracking reaction, hydrocracking catalyst,hydrocracking influence factors. 9.3Lube oil hydrogenation, hydrogenation and heavy oil hydrogenation Lubeoil hydrogenation and hydrogenation treatment, catalytichydro-dewaxing, catalytic hydro-dewaxing of diesel and lube oil,iso-dewaxing, the characteristics of heavy oil hydrogenation andthe process of heavy oil hydrogenation. 9.4Hydrogen production Hydrocarbon-watervapor transformation method, partial oxidation process of heavyoil. Chapterx Production of high octane gasoline components (4 hours) Keypoints of this chapter: alkylation of hydrocarbons, influencefactors of alkylation reaction, catalytic etherification and itsinfluencing factors, catalytic isomerization, isomerizationcatalyst, catalytic polymerization reaction and its influencingfactors. 10.1Catalytic alkylation Alkylationreaction, the influence of raw materials on alkylation reaction,sulfuric acid alkylation, hydrofluoric acid alkylation, newprogress in catalytic alkylation. 10.2Catalytic etherification Catalyticetherification, etherification catalyst, the influence factors ofetherification reaction. 10.3Catalytic isomerization Isomerizationreaction, isomerization catalyst. 10.4Catalytic polymerization Thepolymerization reaction, the non-selective catalyticpolymerization, the selective catalytic polymerization. |